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Record Information

Version

5.0

Status

Detected but not Quantified

Creation Date

2008-10-29 15:19:46 UTC

Update Date

2022-09-22 17:43:57 UTC

HMDB ID

HMDB0011171

Secondary Accession Numbers

HMDB0029153
HMDB11171
HMDB29153

Metabolite Identification

Common Name

gamma-Glutamylleucine

Description

gamma-Glutamylleucine is a dipeptide composed of gamma-glutamate and leucine, and is a proteolytic breakdown product of larger proteins. It belongs to the family of N-acyl-alpha amino acids and derivatives. These are compounds containing an alpha amino acid which bears an acyl group at its terminal nitrogen atom. gamma-Glutamylleucine is an incomplete breakdown product of protein digestion or protein catabolism. Some dipeptides are known to have physiological or cell-signaling effects although most are simply short-lived intermediates on their way to specific amino acid degradation pathways following further proteolysis. gamma-Glutamylleucine is a biomarker for the consumption of whey protein. It is found in urine (PMID: 3782411 ).

Structure

MOL 3D MOL SDF 3D SDF PDB 3D PDB SMILES InChI

HMDB0011171
     RDKit          3D
gamma-Glutamylleucine
 38 37  0  0  0  0  0  0  0  0999 V2000
   -4.4365   -0.4895    0.9861 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.1085   -0.3327    0.1969 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0008   -0.9279    0.9909 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9422    1.1077   -0.1414 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7254    1.4224   -0.9259 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.4883    1.1236   -0.2965 N   0  0  0  0  0  0  0  0  0  0  0  0
    0.4447    0.1955   -0.8107 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.2591   -0.4492   -1.8755 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.7094   -0.0466   -0.0779 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.5667   -1.0601   -0.7773 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.8540   -1.3303   -0.0645 C   0  0  2  0  0  0  0  0  0  0  0  0
    4.6760   -0.1495    0.0758 N   0  0  0  0  0  0  0  0  0  0  0  0
    4.5825   -2.3809   -0.8382 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.9738   -3.4621   -1.0308 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.8668   -2.1265   -1.2998 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7896    2.8136   -1.4474 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.8220    3.5690   -1.3065 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9258    3.2370   -2.0783 O   0  0  0  0  0  0  0  0  0  0  0  0
   -4.6677   -1.5549    0.9684 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.3239   -0.0615    2.0033 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.1665    0.1391    0.4383 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.2749   -0.9334   -0.7194 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3827   -0.1721    1.4687 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3754   -1.6145    0.3705 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4646   -1.5729    1.8080 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.8774    1.4682   -0.6776 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9225    1.7371    0.8103 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7903    0.7873   -1.8781 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.2542    1.6324    0.5829 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.2268    0.9195    0.0601 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.5137   -0.4479    0.9514 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.7629   -0.6754   -1.8000 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.0141   -2.0111   -0.8547 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.6758   -1.7487    0.9378 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.2525    0.6806   -0.3949 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.9145    0.0322    1.0758 H   0  0  0  0  0  0  0  0  0  0  0  0
    6.0192   -1.2324   -1.7512 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5735    3.9150   -1.6798 H   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0
  2  3  1  0
  2  4  1  0
  4  5  1  0
  5  6  1  0
  6  7  1  0
  7  8  2  0
  7  9  1  0
  9 10  1  0
 10 11  1  0
 11 12  1  0
 11 13  1  0
 13 14  2  0
 13 15  1  0
  5 16  1  0
 16 17  2  0
 16 18  1  0
  1 19  1  0
  1 20  1  0
  1 21  1  0
  2 22  1  0
  3 23  1  0
  3 24  1  0
  3 25  1  0
  4 26  1  0
  4 27  1  0
  5 28  1  6
  6 29  1  0
  9 30  1  0
  9 31  1  0
 10 32  1  0
 10 33  1  0
 11 34  1  1
 12 35  1  0
 12 36  1  0
 15 37  1  0
 18 38  1  0
M  END

  Mrv1652305052017392D          

 18 17  0  0  0  0            999 V2000
 2498.9283 2499.5885    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
 2498.9283 2500.4135    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
 2499.6427 2500.8250    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 2500.3572 2500.4135    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 2501.0716 2500.8250    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 2501.7861 2500.4135    0.0000 C   0  0  1  0  0  0  0  0  0  0  0  0
 2502.5005 2500.8250    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 2503.2150 2500.4135    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 2502.5005 2501.6500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 2501.7861 2499.5885    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
 2499.6427 2501.6500    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 2498.2138 2499.1749    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 2497.4994 2499.5885    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 2496.7849 2499.1749    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 2497.4994 2500.4135    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 2499.6427 2499.1749    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
 2500.3572 2499.5885    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
 2499.6427 2498.3499    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  6  0  0  0
  1 12  1  0  0  0  0
  1 16  1  0  0  0  0
  2  3  1  0  0  0  0
  3  4  1  0  0  0  0
  3 11  2  0  0  0  0
  4  5  1  0  0  0  0
  5  6  1  0  0  0  0
  6  7  1  0  0  0  0
  6 10  1  1  0  0  0
  7  8  1  0  0  0  0
  7  9  2  0  0  0  0
 12 13  1  0  0  0  0
 13 14  1  0  0  0  0
 13 15  1  0  0  0  0
 16 17  1  0  0  0  0
 16 18  2  0  0  0  0
M  END
> <DATABASE_ID>
HMDB0011171

> <DATABASE_NAME>
hmdb

> <SMILES>
CC(C)C[C@H](NC(=O)CC[C@H](N)C(O)=O)C(O)=O

> <INCHI_IDENTIFIER>
InChI=1S/C11H20N2O5/c1-6(2)5-8(11(17)18)13-9(14)4-3-7(12)10(15)16/h6-8H,3-5,12H2,1-2H3,(H,13,14)(H,15,16)(H,17,18)/t7-,8-/m0/s1

> <INCHI_KEY>
MYFMARDICOWMQP-YUMQZZPRSA-N

> <FORMULA>
C11H20N2O5

> <MOLECULAR_WEIGHT>
260.2869

> <EXACT_MASS>
260.13722176

> <JCHEM_ACCEPTOR_COUNT>
6

> <JCHEM_ATOM_COUNT>
38

> <JCHEM_AVERAGE_POLARIZABILITY>
26.293109806182578

> <JCHEM_BIOAVAILABILITY>
1

> <JCHEM_DONOR_COUNT>
4

> <JCHEM_FORMAL_CHARGE>
0

> <JCHEM_GHOSE_FILTER>
0

> <JCHEM_IUPAC>
(2S)-2-[(4S)-4-amino-4-carboxybutanamido]-4-methylpentanoic acid

> <ALOGPS_LOGP>
-2.60

> <JCHEM_LOGP>
-2.5341399150650585

> <ALOGPS_LOGS>
-1.76

> <JCHEM_MDDR_LIKE_RULE>
0

> <JCHEM_NUMBER_OF_RINGS>
0

> <JCHEM_PHYSIOLOGICAL_CHARGE>
-1

> <JCHEM_PKA>
4.033435154795595

> <JCHEM_PKA_STRONGEST_ACIDIC>
1.7836665127960734

> <JCHEM_PKA_STRONGEST_BASIC>
9.31207967883151

> <JCHEM_POLAR_SURFACE_AREA>
129.72

> <JCHEM_REFRACTIVITY>
62.25870000000001

> <JCHEM_ROTATABLE_BOND_COUNT>
8

> <JCHEM_RULE_OF_FIVE>
1

> <ALOGPS_SOLUBILITY>
4.48e+00 g/l

> <JCHEM_TRADITIONAL_IUPAC>
(2S)-2-[(4S)-4-amino-4-carboxybutanamido]-4-methylpentanoic acid

> <JCHEM_VEBER_RULE>
0

$$$$

HMDB0011171
     RDKit          3D
gamma-Glutamylleucine
 38 37  0  0  0  0  0  0  0  0999 V2000
   -4.4365   -0.4895    0.9861 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.1085   -0.3327    0.1969 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0008   -0.9279    0.9909 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9422    1.1077   -0.1414 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7254    1.4224   -0.9259 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.4883    1.1236   -0.2965 N   0  0  0  0  0  0  0  0  0  0  0  0
    0.4447    0.1955   -0.8107 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.2591   -0.4492   -1.8755 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.7094   -0.0466   -0.0779 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.5667   -1.0601   -0.7773 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.8540   -1.3303   -0.0645 C   0  0  2  0  0  0  0  0  0  0  0  0
    4.6760   -0.1495    0.0758 N   0  0  0  0  0  0  0  0  0  0  0  0
    4.5825   -2.3809   -0.8382 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.9738   -3.4621   -1.0308 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.8668   -2.1265   -1.2998 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7896    2.8136   -1.4474 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.8220    3.5690   -1.3065 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9258    3.2370   -2.0783 O   0  0  0  0  0  0  0  0  0  0  0  0
   -4.6677   -1.5549    0.9684 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.3239   -0.0615    2.0033 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.1665    0.1391    0.4383 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.2749   -0.9334   -0.7194 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3827   -0.1721    1.4687 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3754   -1.6145    0.3705 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4646   -1.5729    1.8080 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.8774    1.4682   -0.6776 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9225    1.7371    0.8103 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7903    0.7873   -1.8781 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.2542    1.6324    0.5829 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.2268    0.9195    0.0601 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.5137   -0.4479    0.9514 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.7629   -0.6754   -1.8000 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.0141   -2.0111   -0.8547 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.6758   -1.7487    0.9378 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.2525    0.6806   -0.3949 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.9145    0.0322    1.0758 H   0  0  0  0  0  0  0  0  0  0  0  0
    6.0192   -1.2324   -1.7512 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5735    3.9150   -1.6798 H   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0
  2  3  1  0
  2  4  1  0
  4  5  1  0
  5  6  1  0
  6  7  1  0
  7  8  2  0
  7  9  1  0
  9 10  1  0
 10 11  1  0
 11 12  1  0
 11 13  1  0
 13 14  2  0
 13 15  1  0
  5 16  1  0
 16 17  2  0
 16 18  1  0
  1 19  1  0
  1 20  1  0
  1 21  1  0
  2 22  1  0
  3 23  1  0
  3 24  1  0
  3 25  1  0
  4 26  1  0
  4 27  1  0
  5 28  1  6
  6 29  1  0
  9 30  1  0
  9 31  1  0
 10 32  1  0
 10 33  1  0
 11 34  1  1
 12 35  1  0
 12 36  1  0
 15 37  1  0
 18 38  1  0
M  END

HEADER    PROTEIN                                 05-MAY-20   NONE
TITLE     NULL                                                        
COMPND    NULL                                                        
SOURCE    NULL                                                        
KEYWDS    NULL                                                        
EXPDTA    NULL                                                        
AUTHOR    Marvin                                                      
REVDAT   1   05-MAY-20         0                                  
HETATM    1  C   UNK     0    4664.6664665.899   0.000  0.00  0.00           C+0
HETATM    2  N   UNK     0    4664.6664667.439   0.000  0.00  0.00           N+0
HETATM    3  C   UNK     0    4666.0004668.207   0.000  0.00  0.00           C+0
HETATM    4  C   UNK     0    4667.3334667.439   0.000  0.00  0.00           C+0
HETATM    5  C   UNK     0    4668.6674668.207   0.000  0.00  0.00           C+0
HETATM    6  C   UNK     0    4670.0014667.439   0.000  0.00  0.00           C+0
HETATM    7  C   UNK     0    4671.3344668.207   0.000  0.00  0.00           C+0
HETATM    8  O   UNK     0    4672.6684667.439   0.000  0.00  0.00           O+0
HETATM    9  O   UNK     0    4671.3344669.747   0.000  0.00  0.00           O+0
HETATM   10  N   UNK     0    4670.0014665.899   0.000  0.00  0.00           N+0
HETATM   11  O   UNK     0    4666.0004669.747   0.000  0.00  0.00           O+0
HETATM   12  C   UNK     0    4663.3324665.126   0.000  0.00  0.00           C+0
HETATM   13  C   UNK     0    4661.9994665.899   0.000  0.00  0.00           C+0
HETATM   14  C   UNK     0    4660.6654665.126   0.000  0.00  0.00           C+0
HETATM   15  C   UNK     0    4661.9994667.439   0.000  0.00  0.00           C+0
HETATM   16  C   UNK     0    4666.0004665.126   0.000  0.00  0.00           C+0
HETATM   17  O   UNK     0    4667.3334665.899   0.000  0.00  0.00           O+0
HETATM   18  O   UNK     0    4666.0004663.586   0.000  0.00  0.00           O+0
CONECT    1    2   12   16                                                  
CONECT    2    1    3                                                       
CONECT    3    2    4   11                                                  
CONECT    4    3    5                                                       
CONECT    5    4    6                                                       
CONECT    6    5    7   10                                                  
CONECT    7    6    8    9                                                  
CONECT    8    7                                                            
CONECT    9    7                                                            
CONECT   10    6                                                            
CONECT   11    3                                                            
CONECT   12    1   13                                                       
CONECT   13   12   14   15                                                  
CONECT   14   13                                                            
CONECT   15   13                                                            
CONECT   16    1   17   18                                                  
CONECT   17   16                                                            
CONECT   18   16                                                            
MASTER        0    0    0    0    0    0    0    0   18    0   34    0
END

COMPND    HMDB0011171
HETATM    1  C1  UNL     1      -4.437  -0.489   0.986  1.00  0.00           C  
HETATM    2  C2  UNL     1      -3.109  -0.333   0.197  1.00  0.00           C  
HETATM    3  C3  UNL     1      -2.001  -0.928   0.991  1.00  0.00           C  
HETATM    4  C4  UNL     1      -2.942   1.108  -0.141  1.00  0.00           C  
HETATM    5  C5  UNL     1      -1.725   1.422  -0.926  1.00  0.00           C  
HETATM    6  N1  UNL     1      -0.488   1.124  -0.297  1.00  0.00           N  
HETATM    7  C6  UNL     1       0.445   0.196  -0.811  1.00  0.00           C  
HETATM    8  O1  UNL     1       0.259  -0.449  -1.876  1.00  0.00           O  
HETATM    9  C7  UNL     1       1.709  -0.047  -0.078  1.00  0.00           C  
HETATM   10  C8  UNL     1       2.567  -1.060  -0.777  1.00  0.00           C  
HETATM   11  C9  UNL     1       3.854  -1.330  -0.064  1.00  0.00           C  
HETATM   12  N2  UNL     1       4.676  -0.149   0.076  1.00  0.00           N  
HETATM   13  C10 UNL     1       4.583  -2.381  -0.838  1.00  0.00           C  
HETATM   14  O2  UNL     1       3.974  -3.462  -1.031  1.00  0.00           O  
HETATM   15  O3  UNL     1       5.867  -2.126  -1.300  1.00  0.00           O  
HETATM   16  C11 UNL     1      -1.790   2.814  -1.447  1.00  0.00           C  
HETATM   17  O4  UNL     1      -0.822   3.569  -1.307  1.00  0.00           O  
HETATM   18  O5  UNL     1      -2.926   3.237  -2.078  1.00  0.00           O  
HETATM   19  H1  UNL     1      -4.668  -1.555   0.968  1.00  0.00           H  
HETATM   20  H2  UNL     1      -4.324  -0.062   2.003  1.00  0.00           H  
HETATM   21  H3  UNL     1      -5.166   0.139   0.438  1.00  0.00           H  
HETATM   22  H4  UNL     1      -3.275  -0.933  -0.719  1.00  0.00           H  
HETATM   23  H5  UNL     1      -1.383  -0.172   1.469  1.00  0.00           H  
HETATM   24  H6  UNL     1      -1.375  -1.614   0.370  1.00  0.00           H  
HETATM   25  H7  UNL     1      -2.465  -1.573   1.808  1.00  0.00           H  
HETATM   26  H8  UNL     1      -3.877   1.468  -0.678  1.00  0.00           H  
HETATM   27  H9  UNL     1      -2.922   1.737   0.810  1.00  0.00           H  
HETATM   28  H10 UNL     1      -1.790   0.787  -1.878  1.00  0.00           H  
HETATM   29  H11 UNL     1      -0.254   1.632   0.583  1.00  0.00           H  
HETATM   30  H12 UNL     1       2.227   0.920   0.060  1.00  0.00           H  
HETATM   31  H13 UNL     1       1.514  -0.448   0.951  1.00  0.00           H  
HETATM   32  H14 UNL     1       2.763  -0.675  -1.800  1.00  0.00           H  
HETATM   33  H15 UNL     1       2.014  -2.011  -0.855  1.00  0.00           H  
HETATM   34  H16 UNL     1       3.676  -1.749   0.938  1.00  0.00           H  
HETATM   35  H17 UNL     1       4.252   0.681  -0.395  1.00  0.00           H  
HETATM   36  H18 UNL     1       4.915   0.032   1.076  1.00  0.00           H  
HETATM   37  H19 UNL     1       6.019  -1.232  -1.751  1.00  0.00           H  
HETATM   38  H20 UNL     1      -3.573   3.915  -1.680  1.00  0.00           H  
CONECT    1    2   19   20   21
CONECT    2    3    4   22
CONECT    3   23   24   25
CONECT    4    5   26   27
CONECT    5    6   16   28
CONECT    6    7   29
CONECT    7    8    8    9
CONECT    9   10   30   31
CONECT   10   11   32   33
CONECT   11   12   13   34
CONECT   12   35   36
CONECT   13   14   14   15
CONECT   15   37
CONECT   16   17   17   18
CONECT   18   38
END

HMDB0011171
     RDKit          3D
gamma-Glutamylleucine
 38 37  0  0  0  0  0  0  0  0999 V2000
   -4.4365   -0.4895    0.9861 C   0  0  0  0  0  0  0  0  0  0  0  0
   -3.1085   -0.3327    0.1969 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.0008   -0.9279    0.9909 C   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9422    1.1077   -0.1414 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7254    1.4224   -0.9259 C   0  0  2  0  0  0  0  0  0  0  0  0
   -0.4883    1.1236   -0.2965 N   0  0  0  0  0  0  0  0  0  0  0  0
    0.4447    0.1955   -0.8107 C   0  0  0  0  0  0  0  0  0  0  0  0
    0.2591   -0.4492   -1.8755 O   0  0  0  0  0  0  0  0  0  0  0  0
    1.7094   -0.0466   -0.0779 C   0  0  0  0  0  0  0  0  0  0  0  0
    2.5667   -1.0601   -0.7773 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.8540   -1.3303   -0.0645 C   0  0  2  0  0  0  0  0  0  0  0  0
    4.6760   -0.1495    0.0758 N   0  0  0  0  0  0  0  0  0  0  0  0
    4.5825   -2.3809   -0.8382 C   0  0  0  0  0  0  0  0  0  0  0  0
    3.9738   -3.4621   -1.0308 O   0  0  0  0  0  0  0  0  0  0  0  0
    5.8668   -2.1265   -1.2998 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7896    2.8136   -1.4474 C   0  0  0  0  0  0  0  0  0  0  0  0
   -0.8220    3.5690   -1.3065 O   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9258    3.2370   -2.0783 O   0  0  0  0  0  0  0  0  0  0  0  0
   -4.6677   -1.5549    0.9684 H   0  0  0  0  0  0  0  0  0  0  0  0
   -4.3239   -0.0615    2.0033 H   0  0  0  0  0  0  0  0  0  0  0  0
   -5.1665    0.1391    0.4383 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.2749   -0.9334   -0.7194 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3827   -0.1721    1.4687 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3754   -1.6145    0.3705 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.4646   -1.5729    1.8080 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.8774    1.4682   -0.6776 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.9225    1.7371    0.8103 H   0  0  0  0  0  0  0  0  0  0  0  0
   -1.7903    0.7873   -1.8781 H   0  0  0  0  0  0  0  0  0  0  0  0
   -0.2542    1.6324    0.5829 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.2268    0.9195    0.0601 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.5137   -0.4479    0.9514 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.7629   -0.6754   -1.8000 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.0141   -2.0111   -0.8547 H   0  0  0  0  0  0  0  0  0  0  0  0
    3.6758   -1.7487    0.9378 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.2525    0.6806   -0.3949 H   0  0  0  0  0  0  0  0  0  0  0  0
    4.9145    0.0322    1.0758 H   0  0  0  0  0  0  0  0  0  0  0  0
    6.0192   -1.2324   -1.7512 H   0  0  0  0  0  0  0  0  0  0  0  0
   -3.5735    3.9150   -1.6798 H   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0
  2  3  1  0
  2  4  1  0
  4  5  1  0
  5  6  1  0
  6  7  1  0
  7  8  2  0
  7  9  1  0
  9 10  1  0
 10 11  1  0
 11 12  1  0
 11 13  1  0
 13 14  2  0
 13 15  1  0
  5 16  1  0
 16 17  2  0
 16 18  1  0
  1 19  1  0
  1 20  1  0
  1 21  1  0
  2 22  1  0
  3 23  1  0
  3 24  1  0
  3 25  1  0
  4 26  1  0
  4 27  1  0
  5 28  1  6
  6 29  1  0
  9 30  1  0
  9 31  1  0
 10 32  1  0
 10 33  1  0
 11 34  1  1
 12 35  1  0
 12 36  1  0
 15 37  1  0
 18 38  1  0
M  END

View in JSmol View NMR Assignments View Stereo Labels

Synonyms

Value	Source
L-gamma-Glu-L-leu	ChEBI
L-g-Glu-L-leu	Generator
L-Γ-glu-L-leu	Generator
g-Glutamylleucine	Generator
Γ-glutamylleucine	Generator
Γ-glu-leu	HMDB
Γ-L-glu-L-leu	HMDB
Γ-L-glutamyl-L-leucine	HMDB
L-Γ-glutamyl-L-leucine	HMDB
N-Γ-glutamylleucine	HMDB
N-L-Γ-glutamylleucine	HMDB
N-L-Γ-glutamyl-L-leucine	HMDB
gamma-Glu-leu	HMDB
gamma-L-Glu-L-leu	HMDB
gamma-L-Glutamyl-L-leucine	HMDB
L-gamma-Glutamyl-L-leucine	HMDB
N-L-gamma-Glutamylleucine	HMDB
N-L-gamma-Glutamyl-L-leucine	HMDB
g-L-Glutamyl-L-leucine	HMDB
gamma-Glutamyl-leucine	HMDB
N-Γ-L-glutamyl-L-leucine	HMDB
N-gamma-Glutamylleucine	HMDB
N-gamma-L-Glutamyl-L-leucine	HMDB
g-Glu-leu	HMDB
gamma-Glutamylleucine	HMDB, MeSH

Chemical Formula

C₁₁H₂₀N₂O₅

Average Molecular Weight

260.2869

Monoisotopic Molecular Weight

260.13722176

IUPAC Name

(2S)-2-[(4S)-4-amino-4-carboxybutanamido]-4-methylpentanoic acid

Traditional Name

(2S)-2-[(4S)-4-amino-4-carboxybutanamido]-4-methylpentanoic acid

CAS Registry Number

2566-39-4

SMILES

CC(C)C[C@H](NC(=O)CC[C@H](N)C(O)=O)C(O)=O

InChI Identifier

InChI=1S/C11H20N2O5/c1-6(2)5-8(11(17)18)13-9(14)4-3-7(12)10(15)16/h6-8H,3-5,12H2,1-2H3,(H,13,14)(H,15,16)(H,17,18)/t7-,8-/m0/s1

InChI Key

MYFMARDICOWMQP-YUMQZZPRSA-N

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as dipeptides. These are organic compounds containing a sequence of exactly two alpha-amino acids joined by a peptide bond.

Kingdom

Organic compounds

Super Class

Organic acids and derivatives

Class

Carboxylic acids and derivatives

Sub Class

Amino acids, peptides, and analogues

Direct Parent

Dipeptides

Alternative Parents

Substituents

Alpha-dipeptide
Gamma-glutamyl alpha-amino acid
Glutamine or derivatives
Leucine or derivatives
N-acyl-alpha-amino acid
N-acyl-alpha amino acid or derivatives
N-acyl-l-alpha-amino acid
Alpha-amino acid
Alpha-amino acid or derivatives
L-alpha-amino acid
Methyl-branched fatty acid
Branched fatty acid
N-acyl-amine
Fatty acyl
Fatty acid
Dicarboxylic acid or derivatives
Fatty amide
Secondary carboxylic acid amide
Amino acid or derivatives
Carboxamide group
Amino acid
Carboxylic acid
Organic nitrogen compound
Primary aliphatic amine
Organonitrogen compound
Organooxygen compound
Primary amine
Hydrocarbon derivative
Carbonyl group
Organic oxide
Organopnictogen compound
Amine
Organic oxygen compound
Aliphatic acyclic compound

Molecular Framework

Aliphatic acyclic compounds

External Descriptors

glutamyl-L-amino acid (CHEBI:68433 )

Ontology

Physiological effect

Not Available

Disposition

Biological location

Non-excretory biofluid

Biofluid or Excreta

Blood (PMID: 24801555)

Organ

Placenta (HMDB: HMDB0011171)

Excreta

Biofluid or Excreta

Feces (PMID: 27275383)

Source

Endogenous

Endogenous (HMDB: HMDB0011171)

Exogenous

Food

Vegetable

Onion-family vegetable

Garden onion (FooDB: FOOD00006)

Process

Not Available

Role

Not Available

Physical Properties

State

Solid

Experimental Molecular Properties

Property	Value	Reference
Melting Point	Not Available	Not Available
Boiling Point	Not Available	Not Available
Water Solubility	Not Available	Not Available
LogP	Not Available	Not Available

Experimental Chromatographic Properties

Not Available

Predicted Molecular Properties

Property	Value	Source
Water Solubility	4.48 g/L	ALOGPS
logP	-2.6	ALOGPS
logP	-2.5	ChemAxon
logS	-1.8	ALOGPS
pKa (Strongest Acidic)	1.78	ChemAxon
pKa (Strongest Basic)	9.31	ChemAxon
Physiological Charge	-1	ChemAxon
Hydrogen Acceptor Count	6	ChemAxon
Hydrogen Donor Count	4	ChemAxon
Polar Surface Area	129.72 Å²	ChemAxon
Rotatable Bond Count	8	ChemAxon
Refractivity	62.26 m³·mol⁻¹	ChemAxon
Polarizability	26.29 Å³	ChemAxon
Number of Rings	0	ChemAxon
Bioavailability	Yes	ChemAxon
Rule of Five	Yes	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	No	ChemAxon

Predicted Chromatographic Properties

Predicted Collision Cross Sections

Predictor	Adduct Type	CCS Value (Å²)	Reference
DeepCCS	[M+H]+	164.969	30932474
DeepCCS	[M-H]-	162.611	30932474
DeepCCS	[M-2H]-	195.497	30932474
DeepCCS	[M+Na]+	171.062	30932474
AllCCS	[M+H]+	160.7	32859911
AllCCS	[M+H-H2O]+	157.7	32859911
AllCCS	[M+NH4]+	163.5	32859911
AllCCS	[M+Na]+	164.3	32859911
AllCCS	[M-H]-	159.8	32859911
AllCCS	[M+Na-2H]-	160.6	32859911
AllCCS	[M+HCOO]-	161.5	32859911

Predicted Kovats Retention Indices

Underivatized

Metabolite	SMILES	Kovats RI Value	Column Type	Reference
gamma-Glutamylleucine	CC(C)C[C@H](NC(=O)CC[C@H](N)C(O)=O)C(O)=O	3245.8	Standard polar	33892256
gamma-Glutamylleucine	CC(C)C[C@H](NC(=O)CC[C@H](N)C(O)=O)C(O)=O	2028.1	Standard non polar	33892256
gamma-Glutamylleucine	CC(C)C[C@H](NC(=O)CC[C@H](N)C(O)=O)C(O)=O	2359.6	Semi standard non polar	33892256

Derivatized

Derivative Name / Structure	SMILES	Kovats RI Value	Column Type	Reference
gamma-Glutamylleucine,1TMS,isomer #1	CC(C)C[C@H](NC(=O)CC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O	2157.3	Semi standard non polar	33892256
gamma-Glutamylleucine,1TMS,isomer #2	CC(C)C[C@H](NC(=O)CC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C	2166.4	Semi standard non polar	33892256
gamma-Glutamylleucine,1TMS,isomer #3	CC(C)C[C@H](NC(=O)CC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O	2237.2	Semi standard non polar	33892256
gamma-Glutamylleucine,1TMS,isomer #4	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@H](N)C(=O)O)[Si](C)(C)C	2187.3	Semi standard non polar	33892256
gamma-Glutamylleucine,2TMS,isomer #1	CC(C)C[C@H](NC(=O)CC[C@H](N)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	2161.2	Semi standard non polar	33892256
gamma-Glutamylleucine,2TMS,isomer #2	CC(C)C[C@H](NC(=O)CC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O	2244.0	Semi standard non polar	33892256
gamma-Glutamylleucine,2TMS,isomer #3	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@H](N)C(=O)O[Si](C)(C)C)[Si](C)(C)C	2163.1	Semi standard non polar	33892256
gamma-Glutamylleucine,2TMS,isomer #4	CC(C)C[C@H](NC(=O)CC[C@H](N[Si](C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C	2243.0	Semi standard non polar	33892256
gamma-Glutamylleucine,2TMS,isomer #5	CC(C)C[C@@H](C(=O)O[Si](C)(C)C)N(C(=O)CC[C@H](N)C(=O)O)[Si](C)(C)C	2182.1	Semi standard non polar	33892256
gamma-Glutamylleucine,2TMS,isomer #6	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@H](N[Si](C)(C)C)C(=O)O)[Si](C)(C)C	2235.2	Semi standard non polar	33892256
gamma-Glutamylleucine,2TMS,isomer #7	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O	2354.9	Semi standard non polar	33892256
gamma-Glutamylleucine,3TMS,isomer #1	CC(C)C[C@H](NC(=O)CC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	2250.1	Semi standard non polar	33892256
gamma-Glutamylleucine,3TMS,isomer #1	CC(C)C[C@H](NC(=O)CC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	2235.9	Standard non polar	33892256
gamma-Glutamylleucine,3TMS,isomer #1	CC(C)C[C@H](NC(=O)CC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)C(=O)O[Si](C)(C)C	2696.1	Standard polar	33892256
gamma-Glutamylleucine,3TMS,isomer #2	CC(C)C[C@@H](C(=O)O[Si](C)(C)C)N(C(=O)CC[C@H](N)C(=O)O[Si](C)(C)C)[Si](C)(C)C	2187.4	Semi standard non polar	33892256
gamma-Glutamylleucine,3TMS,isomer #2	CC(C)C[C@@H](C(=O)O[Si](C)(C)C)N(C(=O)CC[C@H](N)C(=O)O[Si](C)(C)C)[Si](C)(C)C	2214.4	Standard non polar	33892256
gamma-Glutamylleucine,3TMS,isomer #2	CC(C)C[C@@H](C(=O)O[Si](C)(C)C)N(C(=O)CC[C@H](N)C(=O)O[Si](C)(C)C)[Si](C)(C)C	3153.8	Standard polar	33892256
gamma-Glutamylleucine,3TMS,isomer #3	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)[Si](C)(C)C	2211.2	Semi standard non polar	33892256
gamma-Glutamylleucine,3TMS,isomer #3	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)[Si](C)(C)C	2273.0	Standard non polar	33892256
gamma-Glutamylleucine,3TMS,isomer #3	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)[Si](C)(C)C	2778.5	Standard polar	33892256
gamma-Glutamylleucine,3TMS,isomer #4	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O	2373.4	Semi standard non polar	33892256
gamma-Glutamylleucine,3TMS,isomer #4	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O	2292.7	Standard non polar	33892256
gamma-Glutamylleucine,3TMS,isomer #4	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O	2905.4	Standard polar	33892256
gamma-Glutamylleucine,3TMS,isomer #5	CC(C)C[C@@H](C(=O)O[Si](C)(C)C)N(C(=O)CC[C@H](N[Si](C)(C)C)C(=O)O)[Si](C)(C)C	2226.7	Semi standard non polar	33892256
gamma-Glutamylleucine,3TMS,isomer #5	CC(C)C[C@@H](C(=O)O[Si](C)(C)C)N(C(=O)CC[C@H](N[Si](C)(C)C)C(=O)O)[Si](C)(C)C	2252.6	Standard non polar	33892256
gamma-Glutamylleucine,3TMS,isomer #5	CC(C)C[C@@H](C(=O)O[Si](C)(C)C)N(C(=O)CC[C@H](N[Si](C)(C)C)C(=O)O)[Si](C)(C)C	2818.3	Standard polar	33892256
gamma-Glutamylleucine,3TMS,isomer #6	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C	2375.2	Semi standard non polar	33892256
gamma-Glutamylleucine,3TMS,isomer #6	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C	2320.3	Standard non polar	33892256
gamma-Glutamylleucine,3TMS,isomer #6	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C	2838.7	Standard polar	33892256
gamma-Glutamylleucine,3TMS,isomer #7	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C	2319.1	Semi standard non polar	33892256
gamma-Glutamylleucine,3TMS,isomer #7	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C	2346.9	Standard non polar	33892256
gamma-Glutamylleucine,3TMS,isomer #7	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C	2944.3	Standard polar	33892256
gamma-Glutamylleucine,4TMS,isomer #1	CC(C)C[C@@H](C(=O)O[Si](C)(C)C)N(C(=O)CC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)[Si](C)(C)C	2220.6	Semi standard non polar	33892256
gamma-Glutamylleucine,4TMS,isomer #1	CC(C)C[C@@H](C(=O)O[Si](C)(C)C)N(C(=O)CC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)[Si](C)(C)C	2311.5	Standard non polar	33892256
gamma-Glutamylleucine,4TMS,isomer #1	CC(C)C[C@@H](C(=O)O[Si](C)(C)C)N(C(=O)CC[C@H](N[Si](C)(C)C)C(=O)O[Si](C)(C)C)[Si](C)(C)C	2448.6	Standard polar	33892256
gamma-Glutamylleucine,4TMS,isomer #2	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C	2387.8	Semi standard non polar	33892256
gamma-Glutamylleucine,4TMS,isomer #2	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C	2344.4	Standard non polar	33892256
gamma-Glutamylleucine,4TMS,isomer #2	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C(=O)O[Si](C)(C)C	2542.1	Standard polar	33892256
gamma-Glutamylleucine,4TMS,isomer #3	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C	2360.2	Semi standard non polar	33892256
gamma-Glutamylleucine,4TMS,isomer #3	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C	2391.0	Standard non polar	33892256
gamma-Glutamylleucine,4TMS,isomer #3	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C	2629.6	Standard polar	33892256
gamma-Glutamylleucine,4TMS,isomer #4	CC(C)C[C@@H](C(=O)O[Si](C)(C)C)N(C(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C	2343.7	Semi standard non polar	33892256
gamma-Glutamylleucine,4TMS,isomer #4	CC(C)C[C@@H](C(=O)O[Si](C)(C)C)N(C(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C	2395.2	Standard non polar	33892256
gamma-Glutamylleucine,4TMS,isomer #4	CC(C)C[C@@H](C(=O)O[Si](C)(C)C)N(C(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C	2615.9	Standard polar	33892256
gamma-Glutamylleucine,5TMS,isomer #1	CC(C)C[C@@H](C(=O)O[Si](C)(C)C)N(C(=O)CC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C	2392.0	Semi standard non polar	33892256
gamma-Glutamylleucine,5TMS,isomer #1	CC(C)C[C@@H](C(=O)O[Si](C)(C)C)N(C(=O)CC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C	2427.4	Standard non polar	33892256
gamma-Glutamylleucine,5TMS,isomer #1	CC(C)C[C@@H](C(=O)O[Si](C)(C)C)N(C(=O)CC[C@@H](C(=O)O[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C	2394.7	Standard polar	33892256
gamma-Glutamylleucine,1TBDMS,isomer #1	CC(C)C[C@H](NC(=O)CC[C@H](N)C(=O)O[Si](C)(C)C(C)(C)C)C(=O)O	2394.8	Semi standard non polar	33892256
gamma-Glutamylleucine,1TBDMS,isomer #2	CC(C)C[C@H](NC(=O)CC[C@H](N)C(=O)O)C(=O)O[Si](C)(C)C(C)(C)C	2394.7	Semi standard non polar	33892256
gamma-Glutamylleucine,1TBDMS,isomer #3	CC(C)C[C@H](NC(=O)CC[C@H](N[Si](C)(C)C(C)(C)C)C(=O)O)C(=O)O	2470.9	Semi standard non polar	33892256
gamma-Glutamylleucine,1TBDMS,isomer #4	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@H](N)C(=O)O)[Si](C)(C)C(C)(C)C	2417.0	Semi standard non polar	33892256
gamma-Glutamylleucine,2TBDMS,isomer #1	CC(C)C[C@H](NC(=O)CC[C@H](N)C(=O)O[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C	2625.8	Semi standard non polar	33892256
gamma-Glutamylleucine,2TBDMS,isomer #2	CC(C)C[C@H](NC(=O)CC[C@H](N[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C)C(=O)O	2688.2	Semi standard non polar	33892256
gamma-Glutamylleucine,2TBDMS,isomer #3	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@H](N)C(=O)O[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	2632.9	Semi standard non polar	33892256
gamma-Glutamylleucine,2TBDMS,isomer #4	CC(C)C[C@H](NC(=O)CC[C@H](N[Si](C)(C)C(C)(C)C)C(=O)O)C(=O)O[Si](C)(C)C(C)(C)C	2684.2	Semi standard non polar	33892256
gamma-Glutamylleucine,2TBDMS,isomer #5	CC(C)C[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N(C(=O)CC[C@H](N)C(=O)O)[Si](C)(C)C(C)(C)C	2631.8	Semi standard non polar	33892256
gamma-Glutamylleucine,2TBDMS,isomer #6	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@H](N[Si](C)(C)C(C)(C)C)C(=O)O)[Si](C)(C)C(C)(C)C	2684.9	Semi standard non polar	33892256
gamma-Glutamylleucine,2TBDMS,isomer #7	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)C(=O)O	2792.0	Semi standard non polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #1	CC(C)C[C@H](NC(=O)CC[C@H](N[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C	2903.1	Semi standard non polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #1	CC(C)C[C@H](NC(=O)CC[C@H](N[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C	2775.4	Standard non polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #1	CC(C)C[C@H](NC(=O)CC[C@H](N[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C	2964.9	Standard polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #2	CC(C)C[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N(C(=O)CC[C@H](N)C(=O)O[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	2846.5	Semi standard non polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #2	CC(C)C[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N(C(=O)CC[C@H](N)C(=O)O[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	2769.0	Standard non polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #2	CC(C)C[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N(C(=O)CC[C@H](N)C(=O)O[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	3245.0	Standard polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #3	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@H](N[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	2900.2	Semi standard non polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #3	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@H](N[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	2773.6	Standard non polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #3	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@H](N[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	3015.9	Standard polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #4	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)C(=O)O	3055.2	Semi standard non polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #4	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)C(=O)O	2807.7	Standard non polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #4	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)C(=O)O	3072.1	Standard polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #5	CC(C)C[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N(C(=O)CC[C@H](N[Si](C)(C)C(C)(C)C)C(=O)O)[Si](C)(C)C(C)(C)C	2912.5	Semi standard non polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #5	CC(C)C[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N(C(=O)CC[C@H](N[Si](C)(C)C(C)(C)C)C(=O)O)[Si](C)(C)C(C)(C)C	2775.9	Standard non polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #5	CC(C)C[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N(C(=O)CC[C@H](N[Si](C)(C)C(C)(C)C)C(=O)O)[Si](C)(C)C(C)(C)C	3042.6	Standard polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #6	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C	3040.1	Semi standard non polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #6	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C	2813.8	Standard non polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #6	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C	3029.6	Standard polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #7	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	3028.7	Semi standard non polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #7	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	2825.9	Standard non polar	33892256
gamma-Glutamylleucine,3TBDMS,isomer #7	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	3099.4	Standard polar	33892256
gamma-Glutamylleucine,4TBDMS,isomer #1	CC(C)C[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N(C(=O)CC[C@H](N[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	3089.5	Semi standard non polar	33892256
gamma-Glutamylleucine,4TBDMS,isomer #1	CC(C)C[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N(C(=O)CC[C@H](N[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	2983.2	Standard non polar	33892256
gamma-Glutamylleucine,4TBDMS,isomer #1	CC(C)C[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N(C(=O)CC[C@H](N[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	2914.2	Standard polar	33892256
gamma-Glutamylleucine,4TBDMS,isomer #2	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C	3260.1	Semi standard non polar	33892256
gamma-Glutamylleucine,4TBDMS,isomer #2	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C	3014.4	Standard non polar	33892256
gamma-Glutamylleucine,4TBDMS,isomer #2	CC(C)C[C@H](NC(=O)CC[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)C(=O)O[Si](C)(C)C(C)(C)C	2921.8	Standard polar	33892256
gamma-Glutamylleucine,4TBDMS,isomer #3	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	3262.7	Semi standard non polar	33892256
gamma-Glutamylleucine,4TBDMS,isomer #3	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	3031.3	Standard non polar	33892256
gamma-Glutamylleucine,4TBDMS,isomer #3	CC(C)C[C@@H](C(=O)O)N(C(=O)CC[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	2972.7	Standard polar	33892256
gamma-Glutamylleucine,4TBDMS,isomer #4	CC(C)C[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N(C(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	3255.5	Semi standard non polar	33892256
gamma-Glutamylleucine,4TBDMS,isomer #4	CC(C)C[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N(C(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	3035.0	Standard non polar	33892256
gamma-Glutamylleucine,4TBDMS,isomer #4	CC(C)C[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N(C(=O)CC[C@@H](C(=O)O)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	2964.3	Standard polar	33892256
gamma-Glutamylleucine,5TBDMS,isomer #1	CC(C)C[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N(C(=O)CC[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	3461.1	Semi standard non polar	33892256
gamma-Glutamylleucine,5TBDMS,isomer #1	CC(C)C[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N(C(=O)CC[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	3241.9	Standard non polar	33892256
gamma-Glutamylleucine,5TBDMS,isomer #1	CC(C)C[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N(C(=O)CC[C@@H](C(=O)O[Si](C)(C)C(C)(C)C)N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C	2924.5	Standard polar	33892256

Spectra

GC-MS Spectra

Spectrum Type	Description	Splash Key	Deposition Date	Source	View
Predicted GC-MS	Predicted GC-MS Spectrum - gamma-Glutamylleucine GC-MS (Non-derivatized) - 70eV, Positive	Not Available	2021-10-12	Wishart Lab	View Spectrum
Predicted GC-MS	Predicted GC-MS Spectrum - gamma-Glutamylleucine GC-MS (Non-derivatized) - 70eV, Positive	Not Available	2021-10-12	Wishart Lab	View Spectrum

MS/MS Spectra

Spectrum Type	Description	Splash Key	Deposition Date	Source	View
Experimental LC-MS/MS	LC-MS/MS Spectrum - gamma-Glutamylleucine 35V, Positive-QTOF	splash10-001r-9700000000-ab8893b60e98e1001ce4	2021-09-20	HMDB team, MONA	View Spectrum
Experimental LC-MS/MS	LC-MS/MS Spectrum - gamma-Glutamylleucine 35V, Negative-QTOF	splash10-003r-0910000000-aabd82b48efea4e12f3f	2021-09-20	HMDB team, MONA	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - gamma-Glutamylleucine 10V, Positive-QTOF	splash10-00lr-2790000000-5c22f609f3419b66f92c	2016-06-03	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - gamma-Glutamylleucine 20V, Positive-QTOF	splash10-00lr-5920000000-c6ba6e3d51cd69c276b9	2016-06-03	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - gamma-Glutamylleucine 40V, Positive-QTOF	splash10-0a59-9300000000-b9930e2710d2f35bd3a9	2016-06-03	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - gamma-Glutamylleucine 10V, Negative-QTOF	splash10-0a4i-0390000000-3f84380e6a3d8cd32665	2016-08-03	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - gamma-Glutamylleucine 20V, Negative-QTOF	splash10-05nb-2960000000-9496cdad8fb51a2cf83a	2016-08-03	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - gamma-Glutamylleucine 40V, Negative-QTOF	splash10-008c-9400000000-a22f3c19c909bd949fb2	2016-08-03	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - gamma-Glutamylleucine 10V, Positive-QTOF	splash10-03xr-0290000000-bc2325e96da07defc0e3	2021-09-22	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - gamma-Glutamylleucine 20V, Positive-QTOF	splash10-001i-9500000000-1ff58fb786217f5dab60	2021-09-22	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - gamma-Glutamylleucine 40V, Positive-QTOF	splash10-053r-9000000000-a2e54d332ec42ec1dc2d	2021-09-22	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - gamma-Glutamylleucine 10V, Negative-QTOF	splash10-0006-0290000000-7c126c4b070de4bd4070	2021-09-23	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - gamma-Glutamylleucine 20V, Negative-QTOF	splash10-001i-1920000000-c5a4a154fcf2902b660f	2021-09-23	Wishart Lab	View Spectrum
Predicted LC-MS/MS	Predicted LC-MS/MS Spectrum - gamma-Glutamylleucine 40V, Negative-QTOF	splash10-0006-9500000000-39be620cfa483376cf2d	2021-09-23	Wishart Lab	View Spectrum

NMR Spectra

Spectrum Type	Description	Deposition Date	Source	View
Predicted 1D NMR	¹³C NMR Spectrum (1D, 100 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 100 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 1000 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 1000 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 200 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 200 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 300 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 300 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 400 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 400 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 500 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 500 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 600 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 600 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 700 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 700 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 800 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 800 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹³C NMR Spectrum (1D, 900 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum
Predicted 1D NMR	¹H NMR Spectrum (1D, 900 MHz, D₂O, predicted)	2021-09-25	Wishart Lab	View Spectrum

Biological Properties

Cellular Locations

Not Available

Biospecimen Locations

Blood
Feces
Urine

Tissue Locations

Placenta

Pathways

Not Available

Name	SMPDB/PathBank	KEGG

Normal Concentrations

Biospecimen	Status	Value	Age	Sex	Condition	Reference	Details
Blood	Detected but not Quantified	Not Quantified	Adult (>18 years old)	Both	Normal	24801555	details
Feces	Detected but not Quantified	Not Quantified	Adult (>18 years old)	Both	Normal	29808030	details
Feces	Detected but not Quantified	Not Quantified	Adult (>18 years old)	Both	Normal	27543620	details
Feces	Detected but not Quantified	Not Quantified	Adult (>18 years old)	Both	Normal	25037050	details

Abnormal Concentrations

Biospecimen	Status	Value	Age	Sex	Condition	Reference	Details
Feces	Detected but not Quantified	Not Quantified	Adult (>18 years old)	Both	Colorectal Cancer	27275383	details
Feces	Detected but not Quantified	Not Quantified	Adult (>18 years old)	Both	Colorectal cancer	25037050	details
Feces	Detected but not Quantified	Not Quantified	Adult (>18 years old)	Both	Colorectal cancer	27015276	details
Urine	Detected but not Quantified	Not Quantified	Not Specified	Not Specified	Cancer patients undergoing total body irradiation	31424920	details

Associated Disorders and Diseases

Disease References

Colorectal cancer

Brown DG, Rao S, Weir TL, O'Malia J, Bazan M, Brown RJ, Ryan EP: Metabolomics and metabolic pathway networks from human colorectal cancers, adjacent mucosa, and stool. Cancer Metab. 2016 Jun 6;4:11. doi: 10.1186/s40170-016-0151-y. eCollection 2016. [PubMed:27275383 ]
Sinha R, Ahn J, Sampson JN, Shi J, Yu G, Xiong X, Hayes RB, Goedert JJ: Fecal Microbiota, Fecal Metabolome, and Colorectal Cancer Interrelations. PLoS One. 2016 Mar 25;11(3):e0152126. doi: 10.1371/journal.pone.0152126. eCollection 2016. [PubMed:27015276 ]
Goedert JJ, Sampson JN, Moore SC, Xiao Q, Xiong X, Hayes RB, Ahn J, Shi J, Sinha R: Fecal metabolomics: assay performance and association with colorectal cancer. Carcinogenesis. 2014 Sep;35(9):2089-96. doi: 10.1093/carcin/bgu131. Epub 2014 Jul 18. [PubMed:25037050 ]

Associated OMIM IDs

114500 (Colorectal cancer)

External Links

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FooDB ID

FDB003617

KNApSAcK ID

Not Available

Chemspider ID

133115

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

151023

PDB ID

Not Available

ChEBI ID

68433

Food Biomarker Ontology

Not Available

VMH ID

Not Available

MarkerDB ID

Not Available

Good Scents ID

Not Available

References

Synthesis Reference

Not Available

Material Safety Data Sheet (MSDS)

Not Available

General References

Jandke J, Spiteller G: Dipeptide analysis in human urine. J Chromatogr. 1986 Oct 31;382:39-45. [PubMed:3782411 ]
Brown DG, Rao S, Weir TL, O'Malia J, Bazan M, Brown RJ, Ryan EP: Metabolomics and metabolic pathway networks from human colorectal cancers, adjacent mucosa, and stool. Cancer Metab. 2016 Jun 6;4:11. doi: 10.1186/s40170-016-0151-y. eCollection 2016. [PubMed:27275383 ]
Zheng Y, Yu B, Alexander D, Steffen LM, Boerwinkle E: Human metabolome associates with dietary intake habits among African Americans in the atherosclerosis risk in communities study. Am J Epidemiol. 2014 Jun 15;179(12):1424-33. doi: 10.1093/aje/kwu073. Epub 2014 May 6. [PubMed:24801555 ]
Elshenawy S, Pinney SE, Stuart T, Doulias PT, Zura G, Parry S, Elovitz MA, Bennett MJ, Bansal A, Strauss JF 3rd, Ischiropoulos H, Simmons RA: The Metabolomic Signature of the Placenta in Spontaneous Preterm Birth. Int J Mol Sci. 2020 Feb 4;21(3). pii: ijms21031043. doi: 10.3390/ijms21031043. [PubMed:32033212 ]

Showing metabocard for gamma-Glutamylleucine (HMDB0011171)

MOL for HMDB0011171 (gamma-Glutamylleucine)

3D MOL for HMDB0011171 (gamma-Glutamylleucine)

3D SDF for HMDB0011171 (gamma-Glutamylleucine)

3D-SDF for HMDB0011171 (gamma-Glutamylleucine)

PDB for HMDB0011171 (gamma-Glutamylleucine)

3D PDB for HMDB0011171 (gamma-Glutamylleucine)

SMILES for HMDB0011171 (gamma-Glutamylleucine)

INCHI for HMDB0011171 (gamma-Glutamylleucine)

Structure for HMDB0011171 (gamma-Glutamylleucine)

3D Structure for HMDB0011171 (gamma-Glutamylleucine)

Predicted Collision Cross Sections

Predicted Kovats Retention Indices

Underivatized

Derivatized

GC-MS Spectra

MS/MS Spectra

NMR Spectra