Record Information |
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Version | 5.0 |
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Status | Expected but not Quantified |
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Creation Date | 2012-09-11 20:27:38 UTC |
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Update Date | 2022-03-07 02:54:31 UTC |
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HMDB ID | HMDB0035467 |
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Secondary Accession Numbers | |
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Metabolite Identification |
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Common Name | Glicophenone |
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Description | Glicophenone belongs to the class of organic compounds known as stilbenes. These are organic compounds containing a 1,2-diphenylethylene moiety. Stilbenes (C6-C2-C6 ) are derived from the common phenylpropene (C6-C3) skeleton building block. The introduction of one or more hydroxyl groups to a phenyl ring lead to stilbenoids. Glicophenone has been detected, but not quantified in, herbs and spices. This could make glicophenone a potential biomarker for the consumption of these foods. Based on a literature review very few articles have been published on Glicophenone. |
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Structure | COC1=C(CC=C(C)C)C(O)=CC(O)=C1CC(=O)C1=C(O)C=C(O)C=C1 InChI=1S/C20H22O6/c1-11(2)4-6-14-18(24)10-19(25)15(20(14)26-3)9-17(23)13-7-5-12(21)8-16(13)22/h4-5,7-8,10,21-22,24-25H,6,9H2,1-3H3 |
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Synonyms | Value | Source |
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Glicophenone | MeSH |
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Chemical Formula | C20H22O6 |
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Average Molecular Weight | 358.3851 |
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Monoisotopic Molecular Weight | 358.141638436 |
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IUPAC Name | 2-[4,6-dihydroxy-2-methoxy-3-(3-methylbut-2-en-1-yl)phenyl]-1-(2,4-dihydroxyphenyl)ethan-1-one |
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Traditional Name | 2-[4,6-dihydroxy-2-methoxy-3-(3-methylbut-2-en-1-yl)phenyl]-1-(2,4-dihydroxyphenyl)ethanone |
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CAS Registry Number | Not Available |
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SMILES | COC1=C(CC=C(C)C)C(O)=CC(O)=C1CC(=O)C1=C(O)C=C(O)C=C1 |
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InChI Identifier | InChI=1S/C20H22O6/c1-11(2)4-6-14-18(24)10-19(25)15(20(14)26-3)9-17(23)13-7-5-12(21)8-16(13)22/h4-5,7-8,10,21-22,24-25H,6,9H2,1-3H3 |
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InChI Key | JYRFVDHHGPHQBG-UHFFFAOYSA-N |
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Chemical Taxonomy |
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Description | Belongs to the class of organic compounds known as stilbenes. These are organic compounds containing a 1,2-diphenylethylene moiety. Stilbenes (C6-C2-C6 ) are derived from the common phenylpropene (C6-C3) skeleton building block. The introduction of one or more hydroxyl groups to a phenyl ring lead to stilbenoids. |
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Kingdom | Organic compounds |
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Super Class | Phenylpropanoids and polyketides |
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Class | Stilbenes |
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Sub Class | Not Available |
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Direct Parent | Stilbenes |
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Alternative Parents | |
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Substituents | - Stilbene
- Alkyl-phenylketone
- Methoxyphenol
- Phenylketone
- Phenoxy compound
- Anisole
- Benzoyl
- Methoxybenzene
- Aryl alkyl ketone
- Aryl ketone
- Phenol ether
- Resorcinol
- 1-hydroxy-4-unsubstituted benzenoid
- 1-hydroxy-2-unsubstituted benzenoid
- Alkyl aryl ether
- Phenol
- Monocyclic benzene moiety
- Benzenoid
- Vinylogous acid
- Ketone
- Ether
- Hydrocarbon derivative
- Organic oxygen compound
- Organooxygen compound
- Organic oxide
- Aromatic homomonocyclic compound
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Molecular Framework | Aromatic homomonocyclic compounds |
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External Descriptors | Not Available |
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Ontology |
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Physiological effect | Not Available |
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Disposition | |
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Process | Not Available |
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Role | |
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Physical Properties |
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State | Solid |
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Experimental Molecular Properties | Property | Value | Reference |
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Melting Point | 145 °C | Not Available | Boiling Point | Not Available | Not Available | Water Solubility | Not Available | Not Available | LogP | Not Available | Not Available |
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Experimental Chromatographic Properties | Not Available |
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Predicted Molecular Properties | |
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Predicted Chromatographic Properties | Predicted Collision Cross SectionsPredicted Kovats Retention IndicesUnderivatizedDerivatizedDerivative Name / Structure | SMILES | Kovats RI Value | Column Type | Reference |
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Glicophenone,1TMS,isomer #1 | COC1=C(CC(=O)C2=CC=C(O)C=C2O)C(O)=CC(O[Si](C)(C)C)=C1CC=C(C)C | 3100.8 | Semi standard non polar | 33892256 | Glicophenone,1TMS,isomer #2 | COC1=C(CC=C(C)C)C(O)=CC(O[Si](C)(C)C)=C1CC(=O)C1=CC=C(O)C=C1O | 3124.3 | Semi standard non polar | 33892256 | Glicophenone,1TMS,isomer #3 | COC1=C(CC=C(C)C)C(O)=CC(O)=C1CC(=O)C1=CC=C(O)C=C1O[Si](C)(C)C | 3174.6 | Semi standard non polar | 33892256 | Glicophenone,1TMS,isomer #4 | COC1=C(CC=C(C)C)C(O)=CC(O)=C1CC(=O)C1=CC=C(O[Si](C)(C)C)C=C1O | 3144.5 | Semi standard non polar | 33892256 | Glicophenone,2TMS,isomer #1 | COC1=C(CC(=O)C2=CC=C(O[Si](C)(C)C)C=C2O)C(O)=CC(O[Si](C)(C)C)=C1CC=C(C)C | 2994.2 | Semi standard non polar | 33892256 | Glicophenone,2TMS,isomer #2 | COC1=C(CC(=O)C2=CC=C(O)C=C2O[Si](C)(C)C)C(O)=CC(O[Si](C)(C)C)=C1CC=C(C)C | 3053.6 | Semi standard non polar | 33892256 | Glicophenone,2TMS,isomer #3 | COC1=C(CC=C(C)C)C(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1CC(=O)C1=CC=C(O)C=C1O | 2978.2 | Semi standard non polar | 33892256 | Glicophenone,2TMS,isomer #4 | COC1=C(CC=C(C)C)C(O)=CC(O[Si](C)(C)C)=C1CC(=O)C1=CC=C(O[Si](C)(C)C)C=C1O | 3010.9 | Semi standard non polar | 33892256 | Glicophenone,2TMS,isomer #5 | COC1=C(CC=C(C)C)C(O)=CC(O[Si](C)(C)C)=C1CC(=O)C1=CC=C(O)C=C1O[Si](C)(C)C | 3069.3 | Semi standard non polar | 33892256 | Glicophenone,2TMS,isomer #6 | COC1=C(CC=C(C)C)C(O)=CC(O)=C1CC(=O)C1=CC=C(O[Si](C)(C)C)C=C1O[Si](C)(C)C | 3064.2 | Semi standard non polar | 33892256 | Glicophenone,3TMS,isomer #1 | COC1=C(CC(=O)C2=CC=C(O[Si](C)(C)C)C=C2O[Si](C)(C)C)C(O)=CC(O[Si](C)(C)C)=C1CC=C(C)C | 2980.7 | Semi standard non polar | 33892256 | Glicophenone,3TMS,isomer #2 | COC1=C(CC=C(C)C)C(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1CC(=O)C1=CC=C(O[Si](C)(C)C)C=C1O | 2984.1 | Semi standard non polar | 33892256 | Glicophenone,3TMS,isomer #3 | COC1=C(CC=C(C)C)C(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1CC(=O)C1=CC=C(O)C=C1O[Si](C)(C)C | 2969.5 | Semi standard non polar | 33892256 | Glicophenone,3TMS,isomer #4 | COC1=C(CC=C(C)C)C(O)=CC(O[Si](C)(C)C)=C1CC(=O)C1=CC=C(O[Si](C)(C)C)C=C1O[Si](C)(C)C | 2990.3 | Semi standard non polar | 33892256 | Glicophenone,4TMS,isomer #1 | COC1=C(CC=C(C)C)C(O[Si](C)(C)C)=CC(O[Si](C)(C)C)=C1CC(=O)C1=CC=C(O[Si](C)(C)C)C=C1O[Si](C)(C)C | 3013.3 | Semi standard non polar | 33892256 | Glicophenone,1TBDMS,isomer #1 | COC1=C(CC(=O)C2=CC=C(O)C=C2O)C(O)=CC(O[Si](C)(C)C(C)(C)C)=C1CC=C(C)C | 3380.9 | Semi standard non polar | 33892256 | Glicophenone,1TBDMS,isomer #2 | COC1=C(CC=C(C)C)C(O)=CC(O[Si](C)(C)C(C)(C)C)=C1CC(=O)C1=CC=C(O)C=C1O | 3404.6 | Semi standard non polar | 33892256 | Glicophenone,1TBDMS,isomer #3 | COC1=C(CC=C(C)C)C(O)=CC(O)=C1CC(=O)C1=CC=C(O)C=C1O[Si](C)(C)C(C)(C)C | 3450.7 | Semi standard non polar | 33892256 | Glicophenone,1TBDMS,isomer #4 | COC1=C(CC=C(C)C)C(O)=CC(O)=C1CC(=O)C1=CC=C(O[Si](C)(C)C(C)(C)C)C=C1O | 3430.6 | Semi standard non polar | 33892256 | Glicophenone,2TBDMS,isomer #1 | COC1=C(CC(=O)C2=CC=C(O[Si](C)(C)C(C)(C)C)C=C2O)C(O)=CC(O[Si](C)(C)C(C)(C)C)=C1CC=C(C)C | 3524.4 | Semi standard non polar | 33892256 | Glicophenone,2TBDMS,isomer #2 | COC1=C(CC(=O)C2=CC=C(O)C=C2O[Si](C)(C)C(C)(C)C)C(O)=CC(O[Si](C)(C)C(C)(C)C)=C1CC=C(C)C | 3567.0 | Semi standard non polar | 33892256 | Glicophenone,2TBDMS,isomer #3 | COC1=C(CC=C(C)C)C(O[Si](C)(C)C(C)(C)C)=CC(O[Si](C)(C)C(C)(C)C)=C1CC(=O)C1=CC=C(O)C=C1O | 3488.0 | Semi standard non polar | 33892256 | Glicophenone,2TBDMS,isomer #4 | COC1=C(CC=C(C)C)C(O)=CC(O[Si](C)(C)C(C)(C)C)=C1CC(=O)C1=CC=C(O[Si](C)(C)C(C)(C)C)C=C1O | 3548.3 | Semi standard non polar | 33892256 | Glicophenone,2TBDMS,isomer #5 | COC1=C(CC=C(C)C)C(O)=CC(O[Si](C)(C)C(C)(C)C)=C1CC(=O)C1=CC=C(O)C=C1O[Si](C)(C)C(C)(C)C | 3586.3 | Semi standard non polar | 33892256 | Glicophenone,2TBDMS,isomer #6 | COC1=C(CC=C(C)C)C(O)=CC(O)=C1CC(=O)C1=CC=C(O[Si](C)(C)C(C)(C)C)C=C1O[Si](C)(C)C(C)(C)C | 3595.0 | Semi standard non polar | 33892256 | Glicophenone,3TBDMS,isomer #1 | COC1=C(CC(=O)C2=CC=C(O[Si](C)(C)C(C)(C)C)C=C2O[Si](C)(C)C(C)(C)C)C(O)=CC(O[Si](C)(C)C(C)(C)C)=C1CC=C(C)C | 3668.8 | Semi standard non polar | 33892256 | Glicophenone,3TBDMS,isomer #2 | COC1=C(CC=C(C)C)C(O[Si](C)(C)C(C)(C)C)=CC(O[Si](C)(C)C(C)(C)C)=C1CC(=O)C1=CC=C(O[Si](C)(C)C(C)(C)C)C=C1O | 3669.8 | Semi standard non polar | 33892256 | Glicophenone,3TBDMS,isomer #3 | COC1=C(CC=C(C)C)C(O[Si](C)(C)C(C)(C)C)=CC(O[Si](C)(C)C(C)(C)C)=C1CC(=O)C1=CC=C(O)C=C1O[Si](C)(C)C(C)(C)C | 3650.5 | Semi standard non polar | 33892256 | Glicophenone,3TBDMS,isomer #4 | COC1=C(CC=C(C)C)C(O)=CC(O[Si](C)(C)C(C)(C)C)=C1CC(=O)C1=CC=C(O[Si](C)(C)C(C)(C)C)C=C1O[Si](C)(C)C(C)(C)C | 3682.4 | Semi standard non polar | 33892256 | Glicophenone,4TBDMS,isomer #1 | COC1=C(CC=C(C)C)C(O[Si](C)(C)C(C)(C)C)=CC(O[Si](C)(C)C(C)(C)C)=C1CC(=O)C1=CC=C(O[Si](C)(C)C(C)(C)C)C=C1O[Si](C)(C)C(C)(C)C | 3833.6 | Semi standard non polar | 33892256 |
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| GC-MS SpectraSpectrum Type | Description | Splash Key | Deposition Date | Source | View |
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Predicted GC-MS | Predicted GC-MS Spectrum - Glicophenone GC-MS (Non-derivatized) - 70eV, Positive | splash10-000i-1933000000-f36adaa201e9e0483459 | 2017-09-01 | Wishart Lab | View Spectrum | Predicted GC-MS | Predicted GC-MS Spectrum - Glicophenone GC-MS (4 TMS) - 70eV, Positive | splash10-001i-1092027000-48892b364302084250dd | 2017-10-06 | Wishart Lab | View Spectrum | Predicted GC-MS | Predicted GC-MS Spectrum - Glicophenone GC-MS (Non-derivatized) - 70eV, Positive | Not Available | 2021-10-12 | Wishart Lab | View Spectrum |
MS/MS SpectraSpectrum Type | Description | Splash Key | Deposition Date | Source | View |
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Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - Glicophenone 10V, Positive-QTOF | splash10-0a4i-0129000000-b8ab0e6f49a7a267ea54 | 2016-08-02 | Wishart Lab | View Spectrum | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - Glicophenone 20V, Positive-QTOF | splash10-000i-2923000000-7874e4da0470f7e4e3e1 | 2016-08-02 | Wishart Lab | View Spectrum | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - Glicophenone 40V, Positive-QTOF | splash10-000i-5910000000-8ddba11be5f15918eeb7 | 2016-08-02 | Wishart Lab | View Spectrum | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - Glicophenone 10V, Negative-QTOF | splash10-0a4i-0109000000-51b10d34ba406218a516 | 2016-08-03 | Wishart Lab | View Spectrum | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - Glicophenone 20V, Negative-QTOF | splash10-0a4i-0349000000-719281ff7e0d2e93a425 | 2016-08-03 | Wishart Lab | View Spectrum | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - Glicophenone 40V, Negative-QTOF | splash10-0pb9-1921000000-edf33477d8f0dfc30376 | 2016-08-03 | Wishart Lab | View Spectrum | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - Glicophenone 10V, Negative-QTOF | splash10-0a4i-0029000000-b36110c89788829c237e | 2021-09-23 | Wishart Lab | View Spectrum | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - Glicophenone 20V, Negative-QTOF | splash10-0550-1957000000-7dc166016ecb731446e2 | 2021-09-23 | Wishart Lab | View Spectrum | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - Glicophenone 40V, Negative-QTOF | splash10-0a4i-4958000000-c3b2d5ae683e5eebf199 | 2021-09-23 | Wishart Lab | View Spectrum | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - Glicophenone 10V, Positive-QTOF | splash10-0pb9-0109000000-aa8a962c335e4e9ce242 | 2021-09-25 | Wishart Lab | View Spectrum | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - Glicophenone 20V, Positive-QTOF | splash10-0udr-0914000000-67adce3bec61320b7642 | 2021-09-25 | Wishart Lab | View Spectrum | Predicted LC-MS/MS | Predicted LC-MS/MS Spectrum - Glicophenone 40V, Positive-QTOF | splash10-0fri-0974000000-c1dd393199889533d48b | 2021-09-25 | Wishart Lab | View Spectrum |
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